Alicante is a city and municipality in the Valencian Community, Spain. It is the capital of the province of Alicante and a historic Mediterranean po…Alicante is a city and municipality in the Valencian Community, Spain. It is the capital of the province of Alicante and a historic Mediterranean port. The population of the city was 337,482 as of 2020, the second-largest in the Valencian Community.